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Score the fat cap of the ham in a crosshatch pattern, cutting about 1/4 inch deep into the fat layer.
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Pour 1/2 cup bourbon into a small saucepan over medium heat. Let simmer for 2-3 minutes to burn off harsh alcohol.
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Mix the reduced bourbon with pure maple syrup, brown sugar, Dijon mustard, butter, and apple cider vinegar to create the glaze.
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Place scored ham fat-side up in slow cooker. Pour apple cider vinegar and water (1/2 cup each) on the bottom for steam.
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Set slow cooker to LOW. Plan on approximately 1 hour per pound (10 lbs = about 10 hours of cooking).
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Starting at hour 4, brush glaze over the ham every 30-40 minutes using a pastry brush to build caramelized layers.
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Use an instant-read thermometer to check internal temperature. Ham is ready when it reaches 140°F.
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Remove ham from slow cooker carefully and let rest for 15 minutes before carving.
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Carve ham into thick slices, allowing glaze and accumulated juices to drip over the meat.
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Serve warm with reserved glaze drizzled over slices. Refrigerate leftovers up to 3-4 days, or freeze up to 2 months.